80888-01-3Relevant academic research and scientific papers
Gold(i) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes: towards functionalised azoles
Michon, Christophe,Gilbert, Joachim,Trivelli, Xavier,Nahra, Fady,Cazin, Catherine S. J.,Agbossou-Niedercorn, Francine,Nolan, Steven P.
supporting information, p. 3805 - 3811 (2019/04/17)
Gold(i) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes was developed for the effective synthesis of a series of (Z)-functionalised vinylazoles under solvent free conditions. The catalytic hydrogenation of the resulting enamines leads to substituted saturated azoles in good yields.
CYANOACETYLENE AND ITS DERIVATIVES. IV. NUCLEOPHILIC ADDITION OF AZOLES TO PHENYLCYANOACETYLENE
Mal'kina, A. G.,Skvortsov, Yu. M.,Trofimov, B. A.,Taryashinova, D. S. D.,Chipanina, N. N.,et al.
, p. 2178 - 2183 (2007/10/02)
The nucleophilic addition of azoles (imidazole, 2-methylimidazole, benzimidazole, pyrazole, 3- and 5-methylpyrazole, indazole, 1,2,4-triazole, 3-chloro-5-methyltriazole, benzotriazole) to phenylcyanoacetylene is regioselective and in most cases stereosele
