80922-47-0Relevant articles and documents
Integration of Earth-Abundant Photosensitizers and Catalysts in Metal-Organic Frameworks Enhances Photocatalytic Aerobic Oxidation
Feng, Xuanyu,Pi, Yunhong,Song, Yang,Xu, Ziwan,Li, Zhong,Lin, Wenbin
, p. 1024 - 1032 (2021)
We report here the construction of two metal-organic frameworks (MOFs), Zr6-Cu/Fe-1 and Zr6-Cu/Fe-2, by integrating earth-abundant cuprous photosensitizers (Cu-PSs) and Fe catalysts for photocatalytic aerobic oxidation. Site isolation and pore confinement stabilize both Cu-PSs and Fe catalysts, while the proximity between active centers facilitates electron and mass transfer. Upon visible light irradiation and using O2 as the only oxidant, Zr6-Cu/Fe-1 and Zr6-Cu/Fe-2 efficiently oxidize alcohols and benzylic compounds to afford corresponding carbonyl products with broad substrate scopes, high turnover numbers of up to 500 with a 9.4-fold enhancement over homogeneous analogues, and excellent recyclability in four consecutive runs. Control experiments, spectroscopic evidence, and computational studies revealed the photo-oxidation mechanism: Oxidative quenching of [Cu-PS]? by O2 affords [CuII-PS], which efficiently oxidizes FeIII-OH to generate a hydroxyl radical for substrate oxidation. This work highlights the potential of MOFs in promoting earth-abundant metal-based photocatalysis.
Chromium(VI) Based Oxidants; IV. Zinc Chlorochromate Nonahydrate as an Efficient and Mild Oxidizing Agent
Firouzabadi, H.,Sharifi, A.
, p. 999 - 1002 (2007/10/02)
Zinc chlorochromate nonahydrate is an easily prepared and a cheap oxidizing agent for the oxidation of different types of hydroxy compounds, unsaturated hydrocarbons, and benzylic carbon hydrogen bonds at room temperature in dichloromethane.
