80959-22-4Relevant academic research and scientific papers
Chemoselective Synthesis of Amines from Ammonium Hydroxide and Hydroxylamine in Continuous Flow
Audubert, Clément,Bouchard, Alexanne,Mathieu, Gary,Lebel, Hélène
, p. 14203 - 14209 (2019/01/21)
The chemoselective amination of alkyl bromides and chlorides with aqueous ammonia and hydroxylamine was achieved in continuous flow to produce primary ammonium salts and hydroxylamines in high yields. An in-line workup was designed to isolate the corresponding primary amine, which was also telescoped in further reactions, such as acylation and Paal-Knorr pyrrole synthesis. Monosubstituted epoxides are also compatible with the reaction conditions.
Phase-transfer catalysis for the synthesis of hydroxylamines from oximes using benzyltriethylammonium borohydride in methanol and under solid-phase conditions
Gopalakrishnan, Mannathusamy,Anandabaskaran, Thirunavukkarasu,Sureshkumar, Purusothaman,Thanusu, Jayaraman,Kumaran, Arumugam K.,Kanagarajan, Vijayakumar
, p. 50 - 51 (2007/10/03)
Effective phase-transfer catalysis methodologies for the reduction of oximes to hydroxylamines by a selective and versatile reducing agent, benzyltriethylammonium borohydride (BTEABH), in methanol and under solid-phase conditions are presented.
Herbicidal isoxazolidine-3,5-diones
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, (2008/06/13)
2-Substituted isoxazolidine-3,5-diones and isoxazolidine-3-one-5-thiones exhibit herbicidal activity, controlling effectively the growth of a wide spectrum of grassy and broad-leaved plant species. The preparation and herbicidal activity of the compounds is exemplified.
