80974-08-9Relevant academic research and scientific papers
Branched-chain Sugars. XXIII. Stereoselectivities in the Addition of Nucleophiles to Several 4-Uloses
Matsuzawa, Masafumi,Sato, Ken-ichi,Yasumori, Toshio,Yoshimura, Juji
, p. 3505 - 3509 (2007/10/02)
The stereoselectivities in the 1,2-addition of nucleophiles such as methylmagnesium iodide, vinylmagnesium bromide, and 2-lithio-2-methyl-1,3-dithiane to seven kinds of 4-uloses were examined.The configurations of C-vinyl derivatives obtained were determined from the chemical shifts of α-carbons in 13C-NMR spectra.
