80976-41-6

Upstream product

• 65824-27-3 3,4-dibromobicyclo<3.2.1>octa-2,6-diene 
• 1122-53-8 bicyclo<3.2.1>octa-2,6-dien-4-one 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 80976-66-5 exo-3-chloro-4-hydroxybicyclo<3.2.1>oct-2-ene 
• 4802-43-1 exo-bicyclo<3.2.1>oct-3-en-2-ol 
• 56639-01-1 3-bromobicyclo<3.2.1>octa-3,6-dien-2-ol 
• 1122-53-8 bicyclo<3.2.1>octa-3,6-dien-2-one 
• 3212-77-9 bicyclo<3.2.1>oct-3-en-2-one 

Downstream Products

• 765-72-0 tetracyclo<3.3.0^2,8.0^4,6.0>octane 
• 4096-95-1 bicyclo<3.2.1>octa-2,6-diene 
• 57015-38-0 5-ethynyl-1,3-cyclohexadiene 
• 6909-37-1 semibullvalene 
• 3725-23-3 tricyclo<3.2.1.0^2,7>oct-3-ene 
• 77879-68-6 endo-6-ethynylbicyclo<3.1.0>hex-2-ene 
• 80976-42-7 bicyclo<3.2.1>octa-3,6-dien-2-one tosylhydrazone lithium salt 

Relevant academic research and scientific papers

Srtructure and Reactivity of Bicycloocta-2,6-dien-4-ylidene and Bicyclooct-2-en-4-ylidene. Nucleophilicity of Vinylcarbenes

Carbocyclic carbenes, bicycloocta-2,6-dien-4-ylidene (1) and bicyclooct-2-en-4-ylidene (2), were generated by photolysis of the corresponding diazo compounds, 6 and 10, which were prepared by careful vacuum pyrolysis of the sodium salts of t

Chemistry of 2-Carbenabicyclooctadiene

Pyrolytic decomposition of the lithium or potassium salt of the tosylhydrazone of bicycloocta-3,6-dien-2-one (11) or photolysis of the lithium salt of 11 results in the formation of bicycloocta-2,6-diene (12), tricyclo2,7>oct-3-ene (13), tetracyclo2,8.04,6>octane (14), semibullvalene (15), 5-ethynyl-1,3-cyclohexadiene (16), and endo-6-ethynylbicyclohex-2-ene (17).The formation of the C8H8 fraction (15-17) is ascribed to insertion and rearrangement reactions of singlet 2-carbenabicyclooctadiene, whereas the formation ofthe C8H10 fraction (12-14) appears to be the result of hydrogen abstraction reactions of the corresponding triplet carbene or closely related species.