80994-24-7

Upstream product

• 10064-08-1 (+)-(5S,10S)-12-methoxypodocarpa-8,11,13-triene 
• 66916-98-1 2-(2-bromo-4-methoxyphenyl)acetonitrile 
• 66916-99-2 2-(2-bromo-4-(methoxy)phenyl)acetic acid 
• 768-60-5 4-methoxyphenylacetylen 
• 198631-12-8 2-[2-(2-Bromo-4-methoxyphenyl)ethyl]-3,3-dimethyl-1-methylenecyclohexane 
• 80994-29-2 1-(p-methoxyphenylethynyl)-2,6,6-trimethylcyclohex-1-ene 
• 80994-23-6 trans-1-(p-methoxyphenylethyl)-2,2,6-trimethylcyclohexanol 
• 81026-41-7 3-(p-methoxyphenylethyl)-2,4,4-trimethylcyclohexanol 
• 80994-21-4 trans-1-(p-methoxyphenylethynyl)-2,2,6-trimethylcyclohexanol 
• 2408-37-9 2,2,6-trimethylcyclohexan-1-one 
• 198630-98-7 Ethyl 3-[2-(2-bromo-4-methoxyphenyl)ethyl]-2-methyl-4-oxocyclohex-2-enecarboxylate 
• 198631-02-6 2-[2-(2-Bromo-4-methoxyphenyl)ethyl]-3-methylcyclohex-2-enone 
• 198630-93-2 methyl 2-(2-bromo-4-methoxyphenyl)acetate 
• 198630-96-5 1-bromo-2-(2-bromoethyl)-5-methoxybenzene 

Downstream Products

• 10064-08-1 1,2,3,4,4a,9,10,10a-Octahydro-6-methoxy-1,1,4a-trimethylphenanthrene 
• 80994-30-5 1-(p-methoxyphenylethenyl)-2,6,6-trimethylcyclohex-1-ene 

Relevant academic research and scientific papers

Regioselective aryl radical cyclisation. Part 2. Synthesis of octahydro-1H-dibenzo[a,d]cycloheptenes through 7-endo ring closure

A simple convergent synthesis of trans- and cis-octahydro-1H-dibenzo[a,d]cycloheptenes 15a-c and 16a-c and 20a-c and 21a-c through implementation of a regioselective 7-endo-trig-aryl radical cyclisation of the respective 2-(o-bromoarylethyl)-1-methylenecy

Diterpene Synthesis. Part 2. Acid-catalysed Cyclisation of p-Methoxyphenylethyltrimethylcyclohexanols

The acid-catalysed reactions of two phenylethylcyclohexanols, precursors to tricyclic diterpenoids, are reported.The reaction produced both a bicyclic alkene and a tricyclic molecule; the former was converted into the latter in protic media.Conditions for