80994-31-6

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 1530-38-7 ((4-methoxyphenyl)methyl)triphenylphosphonium bromide 
• 3462-97-3 (4-methoxybenzyl)triphenylphosphonium bromide 
• 41721-03-3 (R)-(+)-α-cyclocitral 
• 14505-74-9 (S)-2,6,6-trimethylcyclohex-2-enecarbaldehyde 
• 81026-41-7 3-(p-methoxyphenylethyl)-2,4,4-trimethylcyclohexanol 

Downstream Products

• 171525-79-4 3-(3-isopropyl-4-methoxyphenethyl)-4,4-dimethyl-2-hydroxymethyl-1-cyclohexene 
• 171525-77-2 3-(3-isopropenyl-4-methoxyphenethyl)-2,4,4-trimethyl-1-cyclohexene 
• 78478-90-7 3-(3-isopropyl-4-methoxyphenethyl)-2,4,4-trimethyl-1-cyclohexene 
• 171525-76-1 3-(3-(2-hydroxy)isopropyl-4-methoxyphenethyl)-2,4,4-trimethyl-1-cyclohexene 

Relevant academic research and scientific papers

Enantioselective total syntheses of 13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one

A enantioselective total synthetic route to (+)-13-acteyl-12-hydroxy-podocarpane-8,11,13-triene-7-one la and (-)-13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one 1b from (S)-(-)-α-cyclocitral 8a and (R)-(+)-α-cyclocitral 8b was developed.

THE TOTAL SYNTHESIS OF (+/-)-ISOPISIFERIN METHYL ETHER

A novel and effective convergent synthesis of (ae)-isopisiferin methyl ether, a rearranged abietane diterpene, having a hexahydrodibenzocycloheptene ring system, was achieved by Wittig reaction, selective hydrogenation and selective oxidation.

Diterpene Synthesis. Part 2. Acid-catalysed Cyclisation of p-Methoxyphenylethyltrimethylcyclohexanols

The acid-catalysed reactions of two phenylethylcyclohexanols, precursors to tricyclic diterpenoids, are reported.The reaction produced both a bicyclic alkene and a tricyclic molecule; the former was converted into the latter in protic media.Conditions for