81002-23-5

Basic information

• Product Name: (S)-3-Methyl-heptanoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester
• Synonyms: (S)-3-Methyl-heptanoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester
• CAS NO: 81002-23-5
• Molecular Weight: 358.565
• Mol File: 81002-23-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-3-Methyl-heptanoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-Methyl-heptanoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(81002-23-5)
• EPA Substance Registry System: (S)-3-Methyl-heptanoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester(81002-23-5)

Safety Data

• Hazardous Substances Data: 81002-23-5(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 81002-21-3 (E)-Hept-2-enoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 10352-88-2 E-hept-2-enoic acid 
• 109-72-8 n-butyllithium 
• 81002-19-9 (1'R,2'S,5'R)-2'-(2''-phenylpropan-2''-yl)-5'-methylcyclohexyl (E)-but-2-enoate 
• 81002-20-2 (+)-8-phenylmenthyl Z-crotonate 
• 65253-04-5 (-)-8-phenylmenthol 

Downstream Products

• 169136-81-6 (-)-(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl tetrolate 
• 81002-20-2 (+)-8-phenylmenthyl Z-crotonate 
• 81002-21-3 (E)-Hept-2-enoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 59614-85-6 (-)-(S)-3-methylheptanoic acid 
• 65253-04-5 (-)-8-phenylmenthol 

Relevant articles and documents

ASYMMETRIC 1,4-ADDITIONS OF COORDINATED MeCu.BF3 TO CHIRAL ENOATES: ENANTIOSELECTIVE SYNTHESES OF (S)-(-)-CITRONELLIC ACID

nBu3P- or cyanide-stabilized RCu.BF3 (R=Me, 4-Me-3-pentenyl) undergo efficient 1,4-additions to neopentylether-shielded trans-enoates.Thus chiral β-substituted carboxylic acids e.g. (S)-citronellic acid were obtained in high e.e. (Schemes 2 and 4).