81023-81-6Relevant academic research and scientific papers
Quasiphosphonium intermediates VI. Crystal structure of neopentyloxy(phenacyl)diphenylphosphonium bromide: a stable Michaelis-Arbuzov intermediate formed in the reaction of neopentyl diphenylphosphinite with phenacyl bromide
Henrick, Kim,Hudson, Harry R.,McPartlin, Mary,Powroznyk, Lubomira,Shaw, Leyla S.
, p. 157 - 163 (1992)
Single crystal X-ray diffraction measurements on the adduct obtained from neopentyl diphenylphosphinite and phenacyl bromide show this Michaelis-Arbuzov intermediate to be a phosphonium compound, with a tetrahedral arrangement of bonds around phosphorus a
QUASIPHOSPHONIUM INTERMEDIATES-IV. ISOLATION AND IDENTIFICATION OF INTERMEDIATES IN THE ARBUZOV AND PERKOW REACTIONS OF NEOPENTYL ESTERS OF PHOSPHORUS(III) ACIDS WITH α-HALOGENOACETOPHENONES
Petnehazy, Imre,Szakal, Gyoengyi,Toeke, Laszlo,Hudson, Harry R.,Powroznyk, Luba,Cooksey, Christopher J.
, p. 4229 - 4236 (2007/10/02)
Crystalline ketophosphonium bromides have been isolated as intermediates in the reactions of trineopentyl phosphite, dineopentyl phenylphosphonite, and neopentyl diphenylphosphinite with α-bromoacetophenone.Thermal decomposition in solution occurs in each
