81026-21-3

Basic information

• Product Name: Oxetane, 2,3,4-trimethyl-2-(1-propynyl)-, (2alpha,3alpha,4alpha)- (9CI)
• Synonyms: Oxetane, 2,3,4-trimethyl-2-(1-propynyl)-, (2alpha,3alpha,4alpha)- (9CI)
• CAS NO: 81026-21-3
• Molecular Formula: C9H14O
• Molecular Weight: 138.20686
• Mol File: 81026-21-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Oxetane, 2,3,4-trimethyl-2-(1-propynyl)-, (2alpha,3alpha,4alpha)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Oxetane, 2,3,4-trimethyl-2-(1-propynyl)-, (2alpha,3alpha,4alpha)- (9CI)(81026-21-3)
• EPA Substance Registry System: Oxetane, 2,3,4-trimethyl-2-(1-propynyl)-, (2alpha,3alpha,4alpha)- (9CI)(81026-21-3)

Safety Data

• Hazardous Substances Data: 81026-21-3(Hazardous Substances Data)

Upstream product

• 624-64-6 trans-2-Butene 
• 7299-55-0 pent-3-yn-2-one 
• 590-18-1 (Z)-2-Butene 

Relevant articles and documents

PHOTOCHEMICAL CYCLOADDITION OF α,β-ACETYLENIC KETONES WITH SIMPLE OLEFINS

Irradiation of 3-pentyn-2-one (1) in the presence of tetramethylethylene, isobutylene, and cis- and trans-2-butene leads to vinyldihydrofurans 3, 5, 6, 8, and 9 (Table 1) in a novel photochemical cycloaddition reaction.A related adduct 13 is formed between tetramethylethylene and 5,5-dimethyl-3-hexyn-2-one (2).A mechanism incorporating an initial biradical that closes to a carbene (eqn 3) is proposed to account for these reactions.