81027-95-4Relevant academic research and scientific papers
Total Synthesis of Carbohydrates: Stereoselective Syntheses of 2,6-Dideoxy-D-arabino-hexose and 2,6-Dideoxy-D-ribo-hexose
Roush, William R.,Brown, Richard J.
, p. 1371 - 1373 (2007/10/02)
Short, highly stereoselective syntheses of the title carbohydrates from allylic alcohol precursors are described.A synthesis of the racemic arabino-deoxyhexose is also described.These syntheses feature the highly regioselective epoxide ring opening reactions of intermediates 7, 11, and 12 and the asymmetric epoxidation-kinetic resolution of allylic alcohol 10.
