81044-73-7

Basic information

• Product Name: 1-p-tolyl-6-methoxybenzindazol-1-imine
• CAS NO: 81044-73-7
• Molecular Weight: 289.337
• Mol File: 81044-73-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-p-tolyl-6-methoxybenzindazol-1-imine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-p-tolyl-6-methoxybenzindazol-1-imine(81044-73-7)
• EPA Substance Registry System: 1-p-tolyl-6-methoxybenzindazol-1-imine(81044-73-7)

Safety Data

• Hazardous Substances Data: 81044-73-7(Hazardous Substances Data)

Upstream product

• 81064-07-5 5-azido-1-hydroxy-4-(p-tolylazo)naphthalene 
• 51642-27-4 5-azidonaphthalen-1-ol 
• 83-55-6 5-amino-1-naphthol 
• 81044-50-0 2-p-Tolylamino-2H-benzo[cd]indazol-5-one 
• 74-88-4 methyl iodide 

Relevant articles and documents

Intramolecular Cyclization of Peri-Substituted 1-Azidonaphthalenes. 3. Structural and Chemical Investigation of 1-(Arylamino)benzindazol-8(and -6)(1H)-ones Produced by Decomposition of Hydroxy-Substituted 8-Azido-1-(arylazo)naphthalenes

Thermal and photochemical decomposition of 8-azido-2-hydroxy-1-(arylazo)naphthalenes 3a-d leads to 1-(arylamino)benzindazol-8(1H)-ones 4a-d in good yields.Analogous results are obtained in the conversion of 5 into 6.The reactions appear to proceed through 1,5-cyclization of the tautomeric hydrazone forms of the azides, and the absence of products that would be expected from nitrene intermediates suggests that the reactions proceed through a concerted mechanism.Evidence is presented to support the benzindazolone structures rather than the isomeric triazines.The ratios of O- and N-alkyl derivatives obtained on alkylation of 4a-d depend on the type of substituent in the arylamino ring and on the bulk of the alkyl group.