81056-10-2Relevant academic research and scientific papers
(5RS,7RS)-7-Methoxy-1,3-dioxacyclooct-5(E)-ene. Synthesis of a Stable Bishetero-trans-cyclooctene, a New Heterocyclic System
Jendralla, Heiner
, p. 201 - 209 (2007/10/02)
Deamination of N-(3,5-dioxabicyclooct-exo-8-yl)-N-nitrosourea (12) with sodium hydrogencarbonate in methanol produced the bicyclic ether 13 and the title compound 14.The latter is quickly isomerized to the cis olefine 15 by a trace of iodine at 30 deg C and gives the cycloadduct 16 with 2,3-dimethyl-1,3-butadiene at 60 deg C. 14 and 15 are the first examples of 1,3-dioxocine derivatives.
