81061-02-1Relevant academic research and scientific papers
Single-Electron-Transfer Pathway in the Coupling of Cyclopropenyl Cations with Organometallic Reagents
Padwa, Albert,Goldstein, Steven I.,Rosenthal, Robert J.
, p. 3278 - 3285 (2007/10/02)
Treatment of diphenylmethylcyclopropenylium perchlorate with various Grignard reagents produced substituted cyclopropenes in excellent yield.Alkyl and vinylic Grignard reagents react at the methylated carbon atom.The substantial increase in formation of t
EFFECTS OF SUBSTITUENTS ON THE TYPE II. PHOTOREACTION OF TETRASUBSTITUTED CYCLOPROPENES
Padwa, Albert,Chou, Chuen S.
, p. 3269 - 3274 (2007/10/02)
The triplet sensitized behavior of a number of 3-alkyl substituted cyclopropenes containing a heteroatom on the side chain has been studied in mechanistic detail.The triplet state was found to undergo H-atom abstraction by a mechanism analogous to the wel
