81096-28-8

Basic information

• Product Name: 1-p-methylphenyl-2,3-dimethyl-2-buten-1-one
• Synonyms: 1-p-methylphenyl-2,3-dimethyl-2-buten-1-one
• CAS NO: 81096-28-8
• Molecular Weight: 188.269
• Mol File: 81096-28-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-p-methylphenyl-2,3-dimethyl-2-buten-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-p-methylphenyl-2,3-dimethyl-2-buten-1-one(81096-28-8)
• EPA Substance Registry System: 1-p-methylphenyl-2,3-dimethyl-2-buten-1-one(81096-28-8)

Safety Data

• Hazardous Substances Data: 81096-28-8(Hazardous Substances Data)

Upstream product

• 81096-21-1 2,3-dimethyl-3-nitro-1-(p-tolyl)-1-butanone 
• 67686-87-7 1-p-methylphenyl-2-methyl-3,3-bis(methylthio)-2-propen-1-one 
• 917-54-4 methyllithium 
• 133480-23-6 2,2-dimethyl-1-(4-methyl phenyl)-3-butene-1-one 
• 5337-93-9 4'-methylpropiophenone 
• 594-71-8 2-chloro-2-nitro-propane 

Relevant articles and documents

Ni-Catalyzed 1,2-Acyl Migration Reactions Triggered by C-C Bond Activation of Ketones

A Ni-catalyzed 1,2-acyl migration triggered by C-C bond cleavage was developed. The process of 1,2-acyl migration followed by olefin isomerization provides a convenient access to α,β-unsaturated ketones, which are well-known building blocks in organic syn

Mechanism of Nucleophilic Addition to the Carbonyl Group. Part III. Evidence for the Reactant-like Nature of the Transition State in the LiAlH4 Reduction of Alkyl Aryl Ketones.

A Hammett-type free energy relationship is established for the LiAlH4 reduction of 1-(X-phenyl)-2,3,3-trimethyl-1-butanones (X = H, p-F, m-F, p-Me, m-Me, p-MeO, m-MeO, p-NMe2 and m-NMe2) in Et2O at 30 deg C.A ρ value of 1.77 has been obtained.Rate ratios