81105-84-2Relevant academic research and scientific papers
A NOVEL STEREOCHEMICAL ASPECT OF NITRO SUGAR DERIVATIVES: "AXIAL" NITRO GROUP PREDOMINATED OVER EQUATORIAL ONE IN EQUILIBRIUM
Sakakibara, Tohru,Minami, Toshiaki,Ishido, Yoshiharu,Sudoh, Rokuro
, p. 67 - 70 (2007/10/02)
2-Nitro sugar derivatives bearing an axial nitro group were proved to be thermodinamically more stable than the corresponding 2-epimers, bearing an equatorial nitro group.
PREPARATION, AND NUCLEOPHILIC ADDITION-REACTIONS, OF 1,5-ANHYDRO-4,6-O-BENZYLIDENE-2,3-DIDEOXY-2-NITRO-D-erythro-HEX-2-ENITOL
Sakakibara, Tohru,Minami, Toshiaki,Ishido, Yoshiharu,Sudoh, Rokuro
, p. 167 - 180 (2007/10/02)
Nucleophilic addition-reactions of the title compound, prepared from the corresponding 3-nitrohex-2-enitol, were investigated under kinetically controlled conditions; such sterically bulky nucleophiles as tert-butyl peroxide and 2,4-pentanedionate ions (e
