81114-93-4Relevant academic research and scientific papers
Ruthenium-catalyzed reaction of alkenyl triflates with zinc thiolates
Imazaki, Yusuke,Shirakawa, Eiji,Hayashi, Tamio
experimental part, p. 10212 - 10215 (2012/01/05)
A ruthenium complex coordinated with 3,4,7,8-tetramethyl-1,10- phenanthroline catalyzed the reaction of alkenyl triflates with zinc dithiolates to give alkenyl sulfides.
Homologation of aldehydes using (phenylthiomethylene) triphenylarsorane: Selective preparation of α-thiophenoxyepoxides and phenylthioenol ethers
Boubia,Mioskowski,Manna,Falck
, p. 6023 - 6026 (2007/10/02)
The title arsonium ylide reacts with aldehydes to give exclusively α-thiophenoxyepoxides in THF and phenylthioenol ethers in THF/HMPA. The former adducts are readily transformed to α-thiophenoxy carbonyls and the latter to one-carbon homologated aldehydes.
