81156-45-8

Basic information

• Product Name: (+/-)-(E)-(2-Hydroxycyclohexylidene)ethanenitrile
• Synonyms: (+/-)-(E)-(2-Hydroxycyclohexylidene)ethanenitrile
• CAS NO: 81156-45-8
• Molecular Weight: 137.181
• Mol File: 81156-45-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (+/-)-(E)-(2-Hydroxycyclohexylidene)ethanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(E)-(2-Hydroxycyclohexylidene)ethanenitrile(81156-45-8)
• EPA Substance Registry System: (+/-)-(E)-(2-Hydroxycyclohexylidene)ethanenitrile(81156-45-8)

Safety Data

• Hazardous Substances Data: 81156-45-8(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 765-87-7 cyclohexane-1,2-dione 
• 6975-71-9 1-cyclohexenylacetonitrile 
• 2537-48-6 diethyl 1-cyanomethylphosphonate 
• 533-60-8 cyclohexanone-2-ol 
• 29625-35-2 (+/-)-2-(7-oxabicyclo[4.1.0]heptyl)ethanenitrile 
• 173948-39-5 (E)-(2-Oxocyclohexylidene)ethanenitrile 

Downstream Products

• 42185-27-3 2-(cyanomethyl)cyclohexanone 
• 90242-33-4 2-(2-hydroxycyclohexyl)acetonitrile 

Relevant articles and documents

PREPARATION OF 4-HYDROXY-2-ALKENENITRILES FROM PHENYLSULFINYLACETONITRILE WITH KETONES OR ALDEHYDES, AND ITS SYNTHETIC APPLICATION TO SUBSTITUTED FURANS

The reaction of phenylsulfinylacetonitrile 1 with ketones or aldehydes gave 4-hydroxy-2-alkenenitrils which were converted to 2- and/or 3-substituted furans by the treatment with diisobutylaluminiumhydride(DIBAL) followed by acid hydrolysis.

Hydroxylated α,β-unsaturated nitriles: Stereoselective synthesis

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