81193-50-2

Basic information

• Product Name: butyl-di-t-butylchlorophosphonium bromide
• Synonyms: butyl-di-t-butylchlorophosphonium bromide
• CAS NO: 81193-50-2
• Molecular Weight: 317.677
• Mol File: 81193-50-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: butyl-di-t-butylchlorophosphonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: butyl-di-t-butylchlorophosphonium bromide(81193-50-2)
• EPA Substance Registry System: butyl-di-t-butylchlorophosphonium bromide(81193-50-2)

Safety Data

• Hazardous Substances Data: 81193-50-2(Hazardous Substances Data)

Upstream product

• 29949-72-2 di(tert-butyl)(n-butyl)phosphine 
• 81193-49-9 butyl-di-t-butylbromophosphonium tribromomethanid 

Relevant articles and documents

REACTIONS OF STERICALLY HINDERED PHOSPHINES WITH CARBON TETRAHALIDES: P-HALOGENYLIDS

1.A study has been made of the effects of steric factors on the reactions of tertiary phosphines with carbon tetrahalides.It is found that in the interaction of sterically hindered phosphine with carbon tetrabromide one gets the formation of bromophosphonium tribromomethylid, which exists at a low temperature, this being in an ionic pair containing the anion CBr3-.A sterically hindered phosphine having hydrogen at the α carbon atom forms P-halogenylids on reaction with carbon tetrahalides. 2.Unstabilized P-halogenylids with unsubstituted methylene and alkylidene gr oups have been synthesized, and also P-halogenylids with trimethylsilyl, methyl sulfide, phosphine, acyl, and aromatic groups on the ylid carbon atom. 3.A study has been made of the reactions of P-chlorylids with chlorine-bearing electrophilic reagents , which give rise to new P-halogenylids.