81240-33-7Relevant academic research and scientific papers
TRANSITION METAL CHEMISTRY OF OXIME CONTAINING LIGANDS, XIII. COBALT(II) COMPLEXES OF SYN-PHENYL-2-PYRIDYLKETOXIME AND SYN-METHYL-2-PYRIDYLKETOXIME
Mohan, M.,Paramhans, B. D.
, p. 219 - 228 (2007/10/02)
Cobalt(II) complexes of the types 2(X)2> (where HL=syn-phenyl-2-pyridylketoxime (Hppk) or syn-methyl-2-pyridylketoxime (Hmpk) and X=Cl, Br, I, NCS, NCSe, 1/2SO4 or OAc) and 2(NO3)>NO3 (where HL=Hppk or Hmpk) were synthesized and characterized by elemental analysis, molar conductance in solution, molecular weight determination, X-ray powder diffraction, magnetic moments (300-78 K), diffuse reflectance and infrared (4000-200 cm-1) spectral measurements.These studies suggest a dimeric halo-bridged cis-distorted octahedral structure for 2(X)2> (where HL=Hppk or Hmpk and X=Cl, Br or I) and a monomeric cis-pseudo-octahedral structure for the remaining cobalt(II) complexes.
