81266-47-9

Basic information

• Product Name: 3-(nitromethyl)cyclopentanone
• Synonyms: 3-(nitromethyl)cyclopentanone
• CAS NO: 81266-47-9
• Molecular Formula: C₆H₉NO₃
• Molecular Weight: 143
• Mol File: 81266-47-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 279.82 °C at 760 mmHg
• Flash Point: 140.959 °C
• Appearance: /
• Density: 1.202 g/cm³
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 3-(nitromethyl)cyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(nitromethyl)cyclopentanone(81266-47-9)
• EPA Substance Registry System: 3-(nitromethyl)cyclopentanone(81266-47-9)

Safety Data

• Hazardous Substances Data: 81266-47-9(Hazardous Substances Data)

Usage

General Description

3-(Nitromethyl)cyclopentanone is an organic compound that falls under the category of a ketone. It consists of a cyclopentanone ring -- a five-member cycloalkane that includes one oxygen atom, and hence, a ketone -- that is substituted with a nitromethyl functional group at the 3-position. Its exact molecular structure, weight, and formula are subject to specific measurement and detection techniques. It can be potentially used in various chemical reactions and syntheses in laboratories. Due to its nitro group, it may also require precautionary handling and storage due to potential reactivity. Clear information about its safety, toxicity, or potential hazards should be referred from a Material Safety Data Sheet (MSDS).

Upstream product

• 930-30-3 cyclopent-2-enone 
• 75-52-5 nitromethane 
• 3001-72-7 DBN 
• 60410-16-4 (1R,4S)-4-hydroxy-2-cyclopentene-1-yl acetate 

Downstream Products

• 1260796-43-7 tert-butyl (3-hydroxycyclopentyl)methylcarbamate 
• 116649-87-7 3-(aminomethyl)cyclopentanol 
• 914930-87-3 N-{6,7-diethoxy-9-[3-(2-methyl-thiazol-4-yl)-phenylamino]-2,3-dihydro-1H-cyclopenta[b]quinolin-1-ylmethyl}-acetamide 
• 914930-89-5 N-{6,7-diethoxy-9-[3-(2-methyl-thiazol-4-yl)-phenylamino]-2,3-dihydro-1H-cyclopenta[b]quinolin-2-ylmethyl}-acetamide 
• 914931-04-7 (6,7-diethoxy-2-nitromethyl-2,3-dihydro-1H-cyclopenta[b]quinolin-9-yl)[3-(2-methylthiazol-4-yl)phenyl]amine 
• 914931-03-6 (6,7-diethoxy-1-nitromethyl-2,3-dihydro-1H-cyclopenta[b]quinolin-9-yl)[3-(2-methylthiazol-4-yl)phenyl]amine 

Relevant articles and documents

Arginine- or lysine-catalyzed Michael addition of nitromethane to α,β-unsaturated ketones in aqueous media

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Asymmetric conjugate addition of nitroalkanes to enones with a chiral α-aminophosphonate catalyst

Chiral diethyl (2R)-tetrahydropyrro-2-ylphosphonate is an effective catalyst for the Michael addition of nitroalkanes to α,β-unsaturated ketones. This study revealed that the hydrate salt of this α-aminophosphonate was found to be a better catalytic speci

CONJUGATE ADDITION OF ALIPHATIC NITRO COMPOUNDS TO 2-CYCLOPENTENONE

Conjugate addition of aliphatic nitro compounds to 2-cyclopentenone has been studied.The best results were obtained by the application of nitronate anions, prepared in situ with methanolic sodium methoxide solution.The adducts have been characterized by elemental analysis and spectroscopic data.