812699-71-1

Basic information

• Product Name: Cyclohexanol,1-[(1R)-1,2-dimethyl-2-propenyl]-5-methyl-2-(1-methylethylidene)-,(1S,5R)-rel-(9CI)
• Synonyms: Cyclohexanol,1-[(1R)-1,2-dimethyl-2-propenyl]-5-methyl-2-(1-methylethylidene)-,(1S,5R)-rel-(9CI)
• CAS NO: 812699-71-1
• Molecular Formula: C15H26O
• Molecular Weight: 222.36634
• Product Categories: METHYL
• Mol File: 812699-71-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanol,1-[(1R)-1,2-dimethyl-2-propenyl]-5-methyl-2-(1-methylethylidene)-,(1S,5R)-rel-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol,1-[(1R)-1,2-dimethyl-2-propenyl]-5-methyl-2-(1-methylethylidene)-,(1S,5R)-rel-(9CI)(812699-71-1)
• EPA Substance Registry System: Cyclohexanol,1-[(1R)-1,2-dimethyl-2-propenyl]-5-methyl-2-(1-methylethylidene)-,(1S,5R)-rel-(9CI)(812699-71-1)

Safety Data

• Hazardous Substances Data: 812699-71-1(Hazardous Substances Data)

Upstream product

• 57253-30-2 tiglyl bromide 
• 89-82-7 pulegone 

Downstream Products

• 112197-59-8 (-)-(2S,4R)-2-hydroxy-2-((1S)-1-methyl-2-oxoprop-1-yl)-4-methylcyclohexanone 

Relevant articles and documents

Stereochemistry of Addition of Allyl Grignard Reagents to (R)-(+)-Pulegone and Other α,β-Ethylenic Ketones

The 1,2-addition of allyl, crotyl, and 2-methyl-2-butenyl Grignard reagents to (R)-(+)-pulegone is regio- and stereoselective.In contrast 3-penten-2-yl and 3-methyl-2-butenyl Grignard reagents undergo 1,2- and 1,4-additions.A "compact approach" stabilized by orbital interaction is the proposed mechanism.A further confirmation was obtained with acyclic enones.