81324-31-4Relevant academic research and scientific papers
Stereoselective reduction of α-bromopenicillanates by tributylphosphine
Ishiwata, Akihiro,Kotra, Lakshmi P.,Miyashita, Kazuyuki,Nagase, Tsuyoshi,Mobashery, Shahriar
, p. 2889 - 2892 (2007/10/03)
Diastereoselective reduction of 6-bromo-6-substituted penicillanate esters has been achieved by treatment with tributylphosphine to give 6-substituted penicillanate esters. This reaction would appear to proceed through a phosphonium β-lactam enolate speci
