81330-04-3Relevant articles and documents
Alkynylmercury Chloride or Acetate as Intermediates in the Mercury(II) Salt-promoted Addition of Aliphatic and Aromatic Amines to Terminal Acetylenes
Barluenga, Jose,Aznar, Fernando,Liz, Ramon,Rodes, Rosa
, p. 1087 - 1091 (2007/10/02)
Arylaminomercuriation of terminal acetylenes has been carried out with aliphatic amines to yield amines and enamines.Phenylethynylmercury chloride is shown to be an intermediate in the mercury(II) salt-promoted addition of aliphatic and aromatic amines to terminal alkynes.
Oxidative Alkyl- and Aryl-aminomercuriation of Prop-2-ynyl Alcohols. Synthesis of N-Substituted α-Iminoketones, α-Di-imines, and α-Aminopropionamidines
Barluenga, Jose,Aznar, Fernando,Liz, Ramon
, p. 1093 - 1098 (2007/10/02)
Addition of primary aliphatic or aromatic amines to prop-2-ynol (1a), 1-phenylprop-2-ynol (5a), and oct-1-yn-3-ol (5b) in the presence of mercury(II) acetate leads to the precipitation of metallic mercury and the formation of the corresponding oxidation p