81435-59-8Relevant academic research and scientific papers
Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes
Groth, Ulrich,Kesenheimer, Christian,Neidh?fer, Jürgen
, p. 1859 - 1862 (2006)
Various cerium allenyl reagents were generated by trans-metallation of allenyl Grignard compounds with CeCl3 and subsequent conversion into homopropargylic alcohols by addition to various aliphatic and aromatic aldehydes. The α-acetylenic alcoh
Generation of Allylic and Related Organozirconiums Through A Highly Effective Zirconium-β-Alkoxide Elimination Reaction
Ito, Hisanaka,Nakamura, Takanori,Taguchi, Takeo,Hanzawa, Yuji
, p. 4507 - 4518 (2007/10/02)
Reactions and characterization of allylic and related zirconium reaegnts (allenic and γ-alkoxyallylic zirconiums) generated by treatment of allylic and/or propargylic ethers with a zirconocene-butene complex ("Cp2Zr") are described.
