81464-57-5Relevant academic research and scientific papers
Reactions of Trifluoroacetyl Isocyanate
Kiemstedt, Wolfgang,Sundermeyer, Wolfgang
, p. 919 - 925 (2007/10/02)
Trifluoroacetyl isocyanate (1) can be obtained from trimethylsilyl isocyanate and trifluoroacetyl chloride. 1 reacts with trifluoroacetamide forming N,N'-bis(trifluoroacetyl)urea (2), which can also be obtained from trifluoroacetyl chloride and urea or N,N'-bis(trimethylsilyl)urea, respectively. 1 reacts with ammonia or various amines forming the trifluoroacetylsubstituted ureas 3 - 6, and hydrazine 7.From 1 and trifluoroacetic acid hexafluorodiacetamide (8) could be obtained. 1 reacts with tert-butylalcohol forming tert-butyl (trifluoroacetyl)carbamate (9).From 1 and N,N-dimethylformamide N,N-dimethyl-N'-(trifluoroacetyl)formamidine (10) could be obtained as well as N-(trifluoroacetyl)pyrrole-2-carboxamide (11) from pyrrole.
