81471-66-1Relevant academic research and scientific papers
Unusual Stereospecificity in the Hydrogenation of an Isopropenyl Function with Wilkinson's Catalyst; A Route to Chiral Methyl Valine
Crout, David H. G.,Lutstorf, Max,Morgan, Philip J.,Adlington, Robert M.,Baldwin, Jack E.,Crimmin, Michael J.
, p. 1175 - 1176 (1981)
Catalytic hydrogenation with H3H in the presence of Wilkinsons's catalyst of (2RS)-(E)--2-acetylamino-3-methylbut-3-enoic acid gave a mixture of (2SR,3SR,4SR)--N-acetylvaline and 2SR,3RS,4SR--N-acetylvaline (6) and (7)
TRITIUM NMR IN INVESTIGATIONS OF BRANCHED-CHAIN AMINO ACID METABOLISM THE SYNTHESIS OF CHIRAL-METHYL VALINE
Crout, D. H. G.,Lutstorf, M.,Morgan, P. J.
, p. 3457 - 3470 (2007/10/02)
A synthesis of chiral-methyl valine has been carried out in order to exploit the principle of the linked configurations of pro, prochiral and prochiral centres in a biosynthetic experiment.
