81475-02-7Relevant academic research and scientific papers
ANIONIC cis-trans ISOMERIZATION OF DIALKYL PERFLUORO(4-METHYL-2-PENTENE)DIOATES. A NON-CLASSICAL EQUILIBRIUM DEPENDENCE
Paleta, Oldrich,Svoboda, Jiri,Dedek, Vaclav
, p. 54 - 58 (2007/10/02)
cis-trans-Isomerization of diethyl, diisopropyl, dibutyl and dicyclohexyl perfluoro(4-methyl-2-pentene)dioates (I-IV) was studied in solutions, containing solid potassium fluoride, in the range 20- 150 degC.The dependence of the cis-trans equilibrium on temperature for compounds I-IV is within the experimental error identical with that found for the dimethyl ester, i.e. it exihibits an extreme at 40-45 degC.This non-classical dependence cannot be described by the van't Hoff equation.The phenomenon is discussed in connection with the so-called cis-effect of fluorine substituents on a double bond.
