81476-85-9Relevant academic research and scientific papers
CLEAVAGE OF SILICON- AND GERMANIUM-TRANSITION METAL BONDS. DEPENDENCE OF THE STEREOCHEMISTRY ON THE NATURE OF THE LIGANDS AND THE GEOMETRY OF COMPLEXES
Cerveau, Genevieve,Colomer, Ernesto,Corriu, Robert J. P.
, p. 33 - 52 (2007/10/02)
The cleavages of some new optically active complexes containing Co-Si (or -Ge), Mn-Si (or -Ge), Re-Ge and W-Ge bonds are described.Electrophiles cleave the Co-Si bond with good retention of configuration at silicon, while the Mn-Si bond is not cleaved und
