81492-14-0Relevant articles and documents
DARSTELLUNG UND SPECTROSKOPISCHE UNTERSUCHUNGEN VON METHYL- UND ISOPROPYLANTIMONHALOGENIDEN
Breunig, H. J.,Kanig, W.
, p. 149 - 160 (2007/10/02)
Halogenations of iPr3Sb yield the dihalides iPr3SbX2 X=Cl, Br, I.These compounds decompose thermally to iPrX and iPr2SbX.Halogenations of iPr2SbX produce unstable trihalides iPr2SbX3, which eliminate iPrX to give iPrSbX2.By this procedure only the bromides and iodides iPr2SbX and iPrSbX2 X=Br, I can be obtained in useful yields and purities.Pure iPrSbCl2 and iPr3Sb are products of exchange reaction of iPr2SbCl.The purity of the known methylcompounds Me2SbX X=Cl, Br, I obtained by decomposition of Me3SbX2 has been examined.MeSbI2 and Me3Sb are formed from Me2SbI.Previously unpublished ir-, 1H-nmr-, and ms-data of iPr3SbX2, R2SbX and RSbX2 R=Me, iPr, X=Cl, Br, I are discussed.