81492-83-3Relevant academic research and scientific papers
STUDY OF THE STEREOCHEMISTRY OF SILVER(I) BIS(PYRIDINE-2-CARBALDEHYDE-IMINE) TRIFLATE COMPLEXES IN SOLUTION: APPLICATION OF INEPT 109Ag AND 1H-NMR
Stein, Gerard C. van,Koten, Gerard van,Brevard, Christian
, p. C27 - C30 (2007/10/02)
IL2>(O3SCF3) complexes have been obtained from the 2/1 reaction of pyridine-2-carbaldehyde-imine (L) with AgO3SCF3.INEPT 109Ag and 1H- NMR studies of 2>(O3SCF3) reveal that the tetrahedral AgIL2 cation of this complex exists below 235 K in two diastereoisomeric forms with a strong preference for one of the molecular configurations (probably the Λ(S)(S)).
