81535-25-3Relevant academic research and scientific papers
Synthesis and Photochemistry of Steroidal β,γ-Unsaturated Ketones: An Approach to Reversible Steroid-Diterpenoid Interconversions
Williams, John R.,Abdel-Magid, Ahmed,Ricker, Wendella,Salama, Hani
, p. 2536 - 2541 (2007/10/02)
4,4-Dimethylandrost-8(14)-en-16-one (3) was synthesized in 14 steps from testosterone.Photolysis of 3 afforded the double-bond migration product 4,4-dimethyl-14β-androst-7-en-16-one (8b) together with a solvent-added product.Photolysis of the β,γ-unsatura
