815620-62-3

Upstream product

• 104-93-8 p-methylanizole 
• 815620-60-1 tert-butyl-[5-(2-methoxy-5-methyl-phenyl)-4,4-dimethyl-hex-5-enyloxy]-dimethyl-silane 
• 815620-59-8 5-(tert-butyl-dimethyl-silanyloxy)-1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pentan-1-one 
• 815620-58-7 5-hydroxy-1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pentan-1-one 
• 603985-03-1 1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pent-4-en-1-one 
• 30574-34-6 1-(2-methoxy-5-methyl phenyl)-2-methyl-propane-1-one 
• 815620-61-2 5-(2-methoxy-5-methyl-phenyl)-4,4-dimethyl-hex-5-en-1-ol 

Downstream Products

• 815620-64-5 [1-(2'-methoxy-5'-methylphenyl)-2,2-dimethylcyclopentyl]-methanol 

Relevant academic research and scientific papers

Synthesis of C-13 oxidised cuparene and herbertane sesquiterpenes via a Paternò-Büchi photocyclisation-oxetane fragmentation strategy: Total synthesis of 1,13-herbertenediol

The intramolecular Paternò-Büchi reaction of 5-aryl-4,4-dimethyl-hex-5-enals has been used to assemble the hindered cyclopentane skeleton of the cuparene and herbertane sesquiterpenes. Regioselective carbon-oxygen bond cleavage in the resulting oxetane is