81571-81-5Relevant academic research and scientific papers
1,2-ANTI DIASTEREOSELECTIVE REDUCTION OF 2-ALKYL-3-HYDROXY-KETONES VIA THEIR SILYL ETHERS.
Bloch, R.,Gilbert, L.,Girard, C.
, p. 1021 - 1024 (1988)
T-butyldimethylsilyl ethers of a range of acyclic 2-alkyl-3-hydroxy-ketones are reduced with lithium aluminium hydride to give with a high 1,2-anti diastereoselective induction syn,anti or anti,anti 2-alkyl-1,3-diols.
Application of a novel 1,3-diol with a benzyl backbone as chiral ligand for asymmetric oxidation of sulfides to sulfoxides
Gogoi, Paramartha,Kotipalli, Trimurthulu,Indukuri, Kiran,Bondalapati, Somasekhar,Saha, Pipas,Saikia, Anil K.
supporting information; experimental part, p. 2726 - 2729 (2012/07/17)
A chiral 1,3-diol with a benzyl backbone has been used for the asymmetric oxidation of sulfides to sulfoxides. Moderate to good yields and enantioselectivity (upto 87% ee) have been observed.
STEREOSELECTIVE REDUCTION OF β-HYDROXYKETONES TO 1,3-DIOLS. HIGHLY SELECTIVE 1,3-ASYMMETRIC INDUCTION VIA BORON CHELATES
Koichi, Narasaka,Pai, Fong-Chang
, p. 2233 - 2238 (2007/10/02)
Highly selective asymmetric induction can be achieved in the reduction of acyclic β-hydroxyketones via boron chelates.Treatment of β-hydroxyketones (1) with tributyl or triisobutylborane and successively with sodium borohydride afforded syn-1,3-diols (3)
