81583-38-2

Basic information

• Product Name: 1-(phenylsulfonyl)tricyclo<4.1.0.0^2,7>heptane
• Synonyms: 1-(phenylsulfonyl)tricyclo<4.1.0.0^2,7>heptane
• CAS NO: 81583-38-2
• Molecular Weight: 234.319
• Mol File: 81583-38-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(phenylsulfonyl)tricyclo<4.1.0.0^2,7>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(phenylsulfonyl)tricyclo<4.1.0.0^2,7>heptane(81583-38-2)
• EPA Substance Registry System: 1-(phenylsulfonyl)tricyclo<4.1.0.0^2,7>heptane(81583-38-2)

Safety Data

• Hazardous Substances Data: 81583-38-2(Hazardous Substances Data)

Upstream product

• 287-13-8 tricyclo[4.1.0.0^2,7]heptane 
• 368-43-4 phenylsulfonyl fluoride 
• 81582-93-6 3-<(phenylsulfonyl)methyl>-1-cyclohexene 
• 237391-54-7 7-endo-6,syn-7-Dibromo-exo-6-phenylsulfonylbicyclo[3.1.1]heptane 
• 67132-78-9 6-endo-chloro-7-syn-(phenylthio)norpinane 
• 132114-84-2 6-endo-phenylsulfonyl-7-syn-bromonorpinane 
• 132114-83-1 6-endo-phenylsulfonyl-7-syn-chloronorpinane 
• 81583-04-2 trans-1,2-epoxy-3-<(phenylsulfonyl)methyl>cyclohexane 

Downstream Products

• 1047637-83-1 exo-7-nitrobicyclo[3.1.1]heptan-6-one 
• 1047632-48-3 endo-7-nitrobicyclo[3.1.1]heptan-6-one 
• 1047637-82-0 methyl exo-6,syn-7-dinitro-exo-6-phenylsulfonylbicyclo[3.1.1]heptane 
• 1047632-47-2 methyl exo-6,syn-7-dinitro-endo-6-phenylsulfonylbicyclo[3.1.1]heptane 
• 1047632-49-4 6,6-dimethoxy-endo-7-nitrobicyclo[3.1.1]heptane 
• 1114966-08-3 exo-6-chloro-syn-7-nitrobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone 
• 462648-19-7 endo-6,syn-7-dichlorobicyclo[3.1.1]hept-exo-6-yl phenyl sulfone 
• 1115244-04-6 endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone 
• 1114966-10-7 6-(dichloromethyl)cyclohex-1-en-1-yl phenyl sulfone 
• 237391-54-7 7-endo-6,syn-7-Dibromo-exo-6-phenylsulfonylbicyclo[3.1.1]heptane 
• 237391-52-5 endo-6-Bromo-exo-6,syn-7-difenylsulfonylbicyclo[3.1.1]heptane 
• 132114-87-5 6-endo-(phenylsulfonyl)norpinane 

Relevant articles and documents

Photochemical reaction of 1-phenylsulfonyltricyclo[4.1.0.02,7]heptane with benzenesulfonyl bromide

Phenylsulfonyltricyclo[4.1.0.02,7]heptane reacts with PhSO2Br under UV light to yield the products of sulfobromination and bromination in 3:1 ratio. Both addition processes are highly cis-stereo-selective. The structure of the bromin

FREE-RADICAL ADDITION OF ARENESULFONYL HAIDES TO TRICYCLO2,7>HEPTANE

The photochemical addition of arenesulfonyl halides ArSO2X (Ar = C6H5, p-CH3C6H4 and X = Cl, Br, I) to tricyclo2,7>heptane takes place at the central bicyclobutane C-C bond and leads to the formation of a mixture of syn and anti adducts