81593-26-2

Basic information

• Product Name: 4-fluoro-3-methylphenylglyoxal
• Synonyms: 4-fluoro-3-methylphenylglyoxal
• CAS NO: 81593-26-2
• Molecular Weight: 166.152
• Mol File: 81593-26-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-fluoro-3-methylphenylglyoxal(CAS DataBase Reference)
• NIST Chemistry Reference: 4-fluoro-3-methylphenylglyoxal(81593-26-2)
• EPA Substance Registry System: 4-fluoro-3-methylphenylglyoxal(81593-26-2)

Safety Data

• Hazardous Substances Data: 81593-26-2(Hazardous Substances Data)

Upstream product

• 369-32-4 1-(4-fluoro-3-methylphenyl)ethanone 

Downstream Products

• 132326-44-4 4-fluoro-3-methylphenylglyoxal benzimidazol-2-ylhydrazone 
• 132326-50-2 4-fluoro-3-methyl-α-nitrophenylglyoxal benzimidazol-2-ylhydrazone 
• 132326-51-3 5-(1H-Benzoimidazol-2-ylazo)-4-(4-fluoro-3-methyl-phenyl)-thiazol-2-ylamine 
• 132326-48-8 α-bromo-4-fluoro-3-methylphenylglyoxal benzimidazol-2-ylhydrazone 
• 81593-44-4 5-(4-Fluoro-3-methyl-phenyl)-imidazolidine-2,4-dione 
• 132326-47-7 2-[(1-Benzyl-1H-benzoimidazol-2-yl)-hydrazono]-1-(4-fluoro-3-methyl-phenyl)-ethanone 

Relevant articles and documents

Exocyclic N-Acyliminium Ion (NAI) Cyclization: Access to Fully Substituted Oxazoles and Furocoumarins

A concise, one-pot route to oxazoles and furocoumarins has been reported. The key step in this transformation involves in situ generation of N-acyliminium ion (NAI) precursor under catalyst and solvent-free conditions and their further transformations promoted by superacid in the same pot. We have also presented the experimental evidence for the involvement of proto-solvated novel exocyclic N-acyliminium ion. Further, the UV-visible and fluorescence studies revealed that few of the compounds reported here exhibited emission of blue light upon irradiation in EtOH in the region of 404-422 nm.