816-78-4Relevant articles and documents
A Catalytic Intermolecular Formal Ene Reaction between Ketone-Derived Silyl Enol Ethers and Alkynes
Holmbo, Stephen D.,Godfrey, Nicole A.,Hirner, Joshua J.,Pronin, Sergey V.
supporting information, p. 12316 - 12319 (2016/10/07)
A catalytic formal ene reaction between ketone-derived silyl enol ethers and terminal alkynes is described. This transformation is uniquely capable of bimolecular assembly of 2-siloxy-1,4-dienes and can be used to access β,?-unsaturated ketones containing quaternary carbons in the α-position.
Manganese Carbonyl and Phase Transfer catalysed, Stereospecific Hydroacylation of Allenes to α,β-Unsaturated Ketones
Satyanarayana, Nistala,Alper, Howard
, p. 8 - 9 (2007/10/02)
Phase transfer (5 mmol dm-3 NaOH, CH2Cl2, cetyltrimethylammonium bromide) catalysed reaction of allenes with carbon monoxide, decacarbonyldimanganese and methyl iodide affords α,β-unsaturated ketones in a stereospecific process.
Catalytic Oxidation of Alk-1-enes to Aldehydes
Feringa, Ben L.
, p. 909 - 910 (2007/10/02)
Aldehydes are the major products of the catalytic oxidation of alk-1-enes with air using a catalyst that comprises (MeCN)2PdClNO2, CuCl2, and a tertiary alcohol.