81617-10-9Relevant academic research and scientific papers
Reaction of 2-Methoxyethyl Hemiacetals with Allylsilanes in the Presence of Titanium Tetrachloride: Regioselective C-O Bond Cleavage of the Unsymmetrical Acetals
Nishiyama, Hisao,Itoh, Kenji
, p. 2496 - 2498 (2007/10/02)
Reaction of 2-methoxyethyl hemiacetals with allylsilanes in the presence of titanium tetrachloride gave the corresponding homoallyl ethers in good yields by the regioselective C-O bond cleavage of the hemiacetals.A new carbon homologative cyclization was
Reaction of Allylsilanes and Monothioacetals in the Presence of Lewis Acids: Regioselectivity in the Cleavage of the Acetals
Nishiyama, Hisao,Narimatsu, Shinzo,Sakuta, Koji,Itoh, Kenji
, p. 459 - 460 (2007/10/02)
Trimethylallylsilane reacts with monothioacetals in the presence of tin(IV) chloride, titanium tetrachloride, or boron trifluoride-diethyl ether to give the homoallyl ethers and homoallyl sulphides.
