81634-68-6

Upstream product

• 131379-62-9 (E)-2-<1,3-bis(trimethylsilyl)-2-propenyl>-1-cyclohexanol 
• 286-20-4 cyclohexene oxide 
• 17891-78-0 1,3-bis(trimethylsilyl)propene 
• 286-20-4 cyclohexane-1,2-epoxide 
• 81634-62-0 3-Bromoallyltrimethylsilane 
• 285-67-6 Cyclopentene oxide 

Downstream Products

• 81634-91-5 Acetic acid (1S,2S)-2-(1-phenylsulfanyl-allyl)-cyclohexyl ester 
• 81634-80-2 Acetic acid (1R,2S)-2-((E)-3-phenylselanyl-propenyl)-cyclohexyl ester 
• 81634-85-7 Acetic acid (1S,2R)-2-(1-hydroxy-allyl)-cyclohexyl ester 
• 81634-97-1 Acetic acid (1R,2S)-2-((E)-3-hydroxy-propenyl)-cyclohexyl ester 
• 81634-75-5 Acetic acid (1S,2R)-2-((E)-3-trimethylsilanyl-propenyl)-cyclohexyl ester 
• 1071214-70-4 C₁₄H₂₅NO₂Si 

Relevant academic research and scientific papers

Lewis acid supported reactions of 1,3-bis(silyl)allyl compounds with epoxides - Inter- and intramolecular versions

Easily available 1,3-bis(silyl)allyl compounds react with epoxides under Lewis acid catalysis to give interesting synthetic building blocks. The course of reaction depends on the stabilization of cationic intermediates by the silicon β-effect.

Synthesis of Vinylcyclopropanes from Epoxides

Ring-opening of epoxides 1 by heteroatom-substituted allyl anions 2 occurs with high regioselectivity.In situ tosylation of the resulting alkoxides 3 or tosylation of the corresponding alcohols 4 yields 4-pentenyl tosylates 5.Anion generation by deprotona

PREPARATION AND SYNTHETIC APPLICATION OF 3-BROMOALLYLTRIMETHYLSILANE AS HYDROXYPROPENYL SYNTHONS

3-Trimethylsilylpropen-1-yl group, as hydroxypropenyl synthons, was easily introduced to several epoxides with the corresponding Grignard reagent derived from 3-bromoallyltrimethylsilane.The introduced skeleton of allyltrimethylsilane was regiospecificall