81650-71-7

Upstream product

• 113680-08-3 5-phenyl-2-(E)-pentenyl-1-trimethylsilane 
• 931-59-9 benzenesulfenyl chloride 
• 108-98-5 thiophenol 
• 103240-88-6 5-phenylpenten-3-yl acetate 

Downstream Products

• 147330-82-3 (E)-5-phenyl-1-triethylgermyl-2-pentane 
• 75950-62-8 PhCH₂CHCHCH₂(tributylstannyl) 

Relevant academic research and scientific papers

Nickel(0) triethyl phosphite complex-catalyzed allylic substitution with retention of regio- and stereochemistry

(Chemical Equation Presented) Nickel(0) triethyl phosphite complex-promoted reaction of allylic acetates with thiols produced allylic sulfides with retention of configuration without allylic rearrangement. A similar reaction of allylic acetates with alcohols and phenols also proceeded with retention of regio- and stereochemistry.

PHENYLSELENODESILYLATION OF ALLYLSILANES AND REGIOSPECIFIC TRANSFORMATION OF ALLYLSILANES TO ALLYLIC ALCOHOLS VIA ALLYLSELENIDES

Allylsilanes were converted regiospecifically to allylselenides by reaction with phenylselenenyl chloride and subsequent treatment with anhydrous tin(II)chloride or florisil.Oxidative work-up of these allylselenides gave the corresponding allylic alcohols regiospecifically.