81655-12-1

Basic information

• Product Name: (1S,5S,6S)-6-Isopropyl-7-methylene-3-phenyl-3-aza-bicyclo[3.2.0]heptane-2,4-dione
• CAS NO: 81655-12-1
• Molecular Weight: 255.316
• Mol File: 81655-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,5S,6S)-6-Isopropyl-7-methylene-3-phenyl-3-aza-bicyclo[3.2.0]heptane-2,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5S,6S)-6-Isopropyl-7-methylene-3-phenyl-3-aza-bicyclo[3.2.0]heptane-2,4-dione(81655-12-1)
• EPA Substance Registry System: (1S,5S,6S)-6-Isopropyl-7-methylene-3-phenyl-3-aza-bicyclo[3.2.0]heptane-2,4-dione(81655-12-1)

Safety Data

• Hazardous Substances Data: 81655-12-1(Hazardous Substances Data)

Upstream product

• 941-69-5 N-phenyl-maleimide 
• 13643-05-5 4-methyl-1,2-pentadiene 

Relevant articles and documents

Cycloaddition Reactions of Allenes with N-Phenylmaleimide. A Two-Step, Diradical-Intermediate Process

The stereoselectivities, chemoselectivities, relative reactivities, and kinetic isotope effects have been determined in the cycloaddition reactions of substituted allenes with N-phenylmaleimide.The comparison of these results with those derived from the studies of the cycloaddition of 1,1-dichloro-2,2-difluoroethene and the radical-chain addition of benzenethiol to allenes strongly indicates that the cycloadditions with N-phenylmaleimide occur via a two step, diradical-intermediate process.The stereochemical features controlling the formation of the stereoisomeric diradical intermediates and their ring closures are discussed.In addition to the cycloaddition processes, competitive ene reactions occur to produce intermediate dienes, which react further to produce 1:2 adducts or nonreactive alkyne-containing 1:1 adducts.These ene reactions also appear to proceed via diradical intermediates.