81665-01-2Relevant academic research and scientific papers
Simple Synthesis of Fluorinated Ene-Ynes via in Situ Generation of Allenes
Jaye, Joseph A.,Sletten, Ellen M.
, p. 4297 - 4307 (2021/07/01)
Herein a bimetallic radical redox-relay strategy is employed to generate alkyl radicals under mild conditions with titanium(III) catalysis and terminated via hydrogen atom transfer with cobalt(II) catalysis to enact base-free isomerizations of N-Bz aziridines to N-Bz allylic amides. This reaction provides an alternative strategy for the synthesis of allylic amides from alkenes via a three-step sequence to accomplish a formal transpositional allylic amination.
PERFLUOROALKYLATION OF CARBANIONS
Umemoto, Teruo,Kuriu, Yuriko
, p. 5197 - 5200 (2007/10/02)
A successful perfluoroalkylation of various carbanions by the use of perfluoroalkylphenyliodonium trifluoromethanesulfonate (FITS) was described.The reactivity of other perfluoroalkyliodonium salt was also examined.
