81669-01-4

Basic information

• Product Name: (3R,5R,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-3,5-dimethyl-tetrahydro-pyran-2-one
• CAS NO: 81669-01-4
• Molecular Weight: 396.602
• Mol File: 81669-01-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,5R,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-3,5-dimethyl-tetrahydro-pyran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,5R,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-3,5-dimethyl-tetrahydro-pyran-2-one(81669-01-4)
• EPA Substance Registry System: (3R,5R,6S)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-3,5-dimethyl-tetrahydro-pyran-2-one(81669-01-4)

Safety Data

• Hazardous Substances Data: 81669-01-4(Hazardous Substances Data)

Upstream product

• 81668-99-7 ((2S,3R,5R,6R)-6-tert-Butoxy-3,5-dimethyl-tetrahydro-pyran-2-ylmethoxy)-tert-butyl-diphenyl-silane 
• 81668-94-2 Acetic acid (2S,3R,6R)-6-tert-butoxy-3-methyl-5-oxo-tetrahydro-pyran-2-ylmethyl ester 
• 3366-47-0 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose 
• 81668-98-6 ((2S,3R,5R,6R)-6-tert-Butoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-methanol 
• 81668-96-4 Acetic acid (2S,3R,6R)-6-tert-butoxy-3-methyl-5-methylene-tetrahydro-pyran-2-ylmethyl ester 
• 79698-71-8 tert-butyl 2,4,6-tri-O-acetyl-3-deoxy-α-D-erythro-hex-2-enopyranoside 
• 81668-95-3 tert-butyl 6-O-acetyl-3,4-dideoxy-α-D-glycero-hex-3-enopyranosid-2-ulose 

Relevant articles and documents

REACTION OF LITHIUM DIMETHYLCUPRATE WITH CONFORMATIONALLY BIASED β-ACYLOXY ENOL ESTERS - REGIO AND STEREOCONTROLLED ACCESS TO FUNCTIONALIZED SIX-CARBON CHIRAL SYNTHONS

Alkyl 2-acyloxy α-D-erythro-hex-2-enopyranoside diesters, readily available from D-hexoses, are versatile intermediates for the expeditious preparation of six-carbon chiral synthons containing alternating and/or consecutive C-methyl and hydroxyl groups.