81674-08-0Relevant academic research and scientific papers
Synthesis of fluoroalkylated alkynes: Via visible-light photocatalysis
Iqbal, Naila,Iqbal, Naeem,Han, Sung Su,Cho, Eun Jin
, p. 1758 - 1762 (2019/02/20)
Fluoroalkylated alkynes, which are versatile building blocks for the synthesis of various biologically active organofluorine compounds, were synthesized from easily available alkynyl halides and fluoroalkyl halides by visible-light photocatalysis. Addition of fluoroalkyl radicals to alkynes and subsequent dehalogenation selectively yielded fluoroalkylated alkynes.
Oxidative coupling of radicals in reactions of compounds of tervalent iodine with trimethylsilyl(phenyl)acetylene
Lermontov,Velikohat'ko,Zefirov
, p. 977 - 978 (2007/10/03)
Reactions of trimethylsilyl(phenyl)acetylene with aryl and alkyl difluoroiodides give coupling products of substituents in high yields.
Perfluoroalkylations of Carbanions with (Perfluoroalkyl)-phenyliodonium Triflates (FITS Reagents)
Umemoto, Teruo,Gotoh, Yoshihiko
, p. 439 - 446 (2007/10/02)
FITS reagents reacted with primary alkylmagnesium halides in THF at -78 deg C to give the corresponding perfluoroalkyl(Rf)-alkanes in moderate to good yields.But an alkyl-lithium or -copper gave a poor yield of the Rf-product.The rea
PERFLUOROALKYLATION OF CARBANIONS
Umemoto, Teruo,Kuriu, Yuriko
, p. 5197 - 5200 (2007/10/02)
A successful perfluoroalkylation of various carbanions by the use of perfluoroalkylphenyliodonium trifluoromethanesulfonate (FITS) was described.The reactivity of other perfluoroalkyliodonium salt was also examined.
