81677-08-9Relevant academic research and scientific papers
CONVERSION OF 3-AZIDO-5-PHENYL-1,2,4-OXADIAZOLE INTO BENZOYL CYANIDE; A NEW THERMAL FRAGMENTATION
Choi, P.,Rees, C.W.,Smith, E.H.
, p. 121 - 124 (2007/10/02)
Flash vacuum pyrolysis of 3-azido-5-phenyl-1,2,4-oxadiazole gives benzoyl cyanide for which a mechanism involving the formation and fragmentation of N-benzoylpentaazafulvene is proposed.
REACTION OF 3-AZIDO-5-PHENYL-1,2,4-OXADIAZOLE WITH DIMETHYLFORMAMIDE, A NEW DEOXYGENATIVE COUPLING REACTION
Choi, P.,Rees, C.W.,Smith, E.H.
, p. 125 - 128 (2007/10/02)
When 3-bromo-5-phenyl-1,2,4-oxadiazole is heated with sodium azide in anhydrous dimethylformamide at 130 deg C, 3-dimethylamino and 3-dimethylaminomethyleneamino-5-phenyl-1,2,4-oxadiazole are formed, the latter by a new deoxygenative coupling of the azide
