81693-62-1

Basic information

• Product Name: 2-Pentanol, 5-amino-
• CAS NO: 81693-62-1
• Molecular Formula: C5H13NO
• Molecular Weight: 103.164
• Mol File: 81693-62-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Pentanol, 5-amino-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentanol, 5-amino-(81693-62-1)
• EPA Substance Registry System: 2-Pentanol, 5-amino-(81693-62-1)

Safety Data

• Hazardous Substances Data: 81693-62-1(Hazardous Substances Data)

Upstream product

• 1039627-20-7 CH₂CH(CH₂)3NH₂BH₃ 
• 123-91-1 1,4-dioxane 
• 38802-24-3 4-hydroxyvaleric amide 

Relevant articles and documents

Amine-directed hydroboration: Scope and limitations

Iodine activation induces intramolecular hydroboration of homoallylic and bis-homoallylic amine boranes with good to excellent control of regiochemistry compared to control experiments using excess THF?BH3. Deuterium labeling and other evidence confirm that the iodine-induced hydroboration reaction of homoallylic amine boranes occurs via an intramolecular mechanism equivalent to the classical 4-center process and without competing retro-hydroboration. Longer carbon chain tethers result in lower regioselectivity, whereas the shorter tether in allylic amines results in a switch to dominant intermolecular hydroboration. Regioselectivity in THF?BH3 control experiments is higher for the allylic amine boranes compared to the iodine activation experiments, whereas the reverse is true for homoallylic amine borane activation.