81710-27-2Relevant academic research and scientific papers
SYNTHESIS, PROPERTIES, AND REDUCTION OF 1,8-NAPHTHYLENEBIS(DIPHENYLCYCLOPROPENIUM) DICATION
Komatsu, Koichi,Arai, Mikiro,Okamoto, Kunio
, p. 91 - 94 (1982)
Synthesis, properties, and the result of one-electron reduction are described for the title compound, which is the first example of the stable dication containing two cationic ring in a close face-to-face arrangement.
Reaction of 1,8-Bis(phenylethynyl)naphthalene with Phenylchlorocarbene: Formation of an Intermolecular Cyclization Product from Carbene Monoadduct and of 1,8-Naphthylenebis(diphenylcyclopropenylium) Dication from the Bisadduct
Komatsu, Koichi,Arai, Mikiro,Hattori, Yoshiyuki,Fukuyama, Keiichi,Katsube, Yukiteru,Okamoto, Kunio
, p. 2183 - 2192 (2007/10/02)
The reactions of 1,8-bis(phenylethynyl)naphthalene (4) with phenylchloro- and dichlorocarbenes and chemistry of the obtained products have been studied.The reaction of 4 with 1 equiv of phenylchlorocarbene exclusively affords spirocyclopropene 8, whose st
