81718-49-2Relevant academic research and scientific papers
REAKTIONEN VON N-SULFINYLVERBINDUNGEN, XVI. Neue Wege zu Sulfinsaeurederivaten ueber En-Addukte von N-Sulfinyl-nonafluorbutansulfonamid
Ruminy, Arno J.,Kresze, Guenter
, p. 49 - 56 (2007/10/02)
2-Alkenesulfinic acid esters and -sulfoxides may be prepared advantageously from the products of ene reactions of N-sulfinyl nonafluorobutane sulfonamide with alkenes.Unexpectedly, the reaction of these ene adducts with diazomethane yields sulfimidic acid esters.
Reactions of N-Sulfinyl Compounds, XV. - Synthesis of 2-Alkenesulfinic Acid Amides - Structure-Reactivity Relationships for N-Sulfinyl Compounds as Enophiles
Bussas, Reinhard,Kresze, Guenter
, p. 545 - 563 (2007/10/02)
The reactivity of N-sulfinyl compounds R6NSO 2 in ene-reactions shows a large variation depending on the nature of the group R6.Haloalkanesulfonamide derivatives react even with very unreactive alkenes.The scope of this method for the synthesis of sulfinic acid amides and the side reactions are discussed.
