817195-71-4

Basic information

• Product Name: Benzenamine, N-(2-furanylmethylene)-4-methyl-, N-oxide (9CI)
• Synonyms: Benzenamine, N-(2-furanylmethylene)-4-methyl-, N-oxide (9CI)
• CAS NO: 817195-71-4
• Molecular Formula: C₁₂H₁₁NO₂
• Molecular Weight: 201.22124
• Product Categories: METHYL
• Mol File: 817195-71-4.mol
• Article Data: 3

Chemical Properties

• Melting Point: 130-132 °C
• Boiling Point: 342.3±44.0 °C(Predicted)
• Appearance: /
• Density: 1.170±0.06 g/cm3(Predicted)
• PKA: 0.08±0.53(Predicted)
• CAS DataBase Reference: Benzenamine, N-(2-furanylmethylene)-4-methyl-, N-oxide (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(2-furanylmethylene)-4-methyl-, N-oxide (9CI)(817195-71-4)
• EPA Substance Registry System: Benzenamine, N-(2-furanylmethylene)-4-methyl-, N-oxide (9CI)(817195-71-4)

Safety Data

• Hazardous Substances Data: 817195-71-4(Hazardous Substances Data)

Upstream product

• 98-01-1 furfural 
• 623-10-9 N-(4-methylphenyl)hydroxylamine 
• 99-99-0 1-methyl-4-nitrobenzene 

Downstream Products

• 195214-26-7 (CH₃)2SnCl₂(C₁₁H₈NO₂CH₃) 

Relevant articles and documents

Water-Soluble Maleimide-Modified Gold Nanoparticles (AuNPs) as a Platform for Cycloaddition Reactions

Maleimide-terminated triethylene glycol thiolate monolayer-protected gold nanoparticles (Mal-EG4-AuNPs) with a core size of 2.5±0.7 nm were prepared. Mal-EG4-AuNPs were modified in high yields via interfacial 1,3-dipolar cycloadditio

Magnesium iodide promoted reactions of nitrones with cyclopropanes: A synthesis of tetrahydro-1,2-oxazines

Anhydrous magnesium iodide (MgI2) is shown to be an effective promoter of the "homo 3+2" dipolar cycloaddition of nitrones with 1,1-cyclopropane diesters. In almost all cases the products tetrahydro-1,2-oxazines are formed in excellent yields. The reactions are highly diastereoselective for a cis relationship between the substitutents at the 3- and 6-positions on the tetrahydrooxazine ring. As an alternative to using a preformed nitrone, the reaction may be performed in a 3-component sense by combining an aldehyde, an hydroxylamine, and the cyclopropane in the presence of catalytic MgI2.