81728-68-9Relevant articles and documents
ESTERIFICATION OF CARBOXYLIC ACIDS WITH ALLYL ALCOHOL
D'yachkov, A. I.,Likhterov, V. R.,Etlis, V. S.
, p. 829 - 832 (2007/10/02)
The kinetics of the esterification of substituted carboxylic acids with allyl alcohol were studied.The reaction is of first order in the catalyst and in the substrate, and the equilibrium under the investigated conditions is shifted toward the formation of the ester.The observed enthalpy of activation does not depend on the substituent, and the difference in the reactivities of the investigated compounds is determined entirely by the entropy component of the free energy.